http://dev.mysql.com/doc/refman/5.1/en/show-columns.html
The Key field indicates whether the column is indexed:
If Key is empty, the column either is not indexed or is indexed only as a secondary column in a multiple-column, non-unique index.
If Key is PRI, the column is a PRIMARY KEY or is one of the columns in a multiple-column PRIMARY KEY.
If Key is UNI, the column is the first column of a unique-valued index that cannot contain NULL values.
If Key is MUL, multiple occurrences of a given value are allowed within the column.
The column is the first column of a non-unique index
or a unique-valued index that can contain NULL values.
If more than one of the Key values applies to a given column of a table,
Key displays the one with the highest priority, in the order PRI, UNI, MUL.
A UNIQUE index may be displayed as PRI if it cannot contain NULL values and there is no PRIMARY KEY in the table.
A UNIQUE index may display as MUL if several columns form a composite UNIQUE index;
although the combination of the columns is unique, each column can still hold multiple occurrences of a given value.